Hello ConnMan:
I admire your creative thinking. The optical-out on your Focusrite Pro40 is designed to connect to an optical-in on an 8 channel ADAT device like this one for example:
http://www.sweetwater.com/store/detail/ADA8200
Neverthless, your 7.1 home surround system relies on Dolby Digital (or maybe DTS) encoding to know how to distribute which sound to where. Currently HW doesn't support native Dobly encoding.
What you could do is experiment with your receiver settings as they usually have options to simulate different surround sound (multi-speaker) effects from just a stereo signal.
Danny B.